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CM38_1193.pdf
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Violet-colored diopside from southern Baffin Island, Nunavut, Canada, occurs in calc-silicate lenses with marialite, pargasite, phlogopite, and other minerals. The diopside has a vitreous luster, is homogeneous, and has a basal parting with subtle cleavage. Its optical properties include indices of refraction nα 1.670(1), nβ 1.675(1), and nγ 1.695(1), with a 2VZ angle of 57.6(5)° at 589 nm and no pleochroism. The calculated density is 3.30 g/cm3. The empirical formula is (Ca0.96Na0.04)(Mg0.86Al0.06Fe2+0.05Ti4+0.02)(Si1.89Al0.11)O5.93OH0.07. The violet color is due to intervalence charge-transfer between Fe2+ and Ti4+ at the M1 site, observable due to the low overall concentration of Fe in the diopside.

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Violet-colored diopside from southern Baffin Island, Nunavut, Canada, occurs in calc-silicate lenses with marialite, pargasite, phlogopite, and other minerals.

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