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The effect of Ca-Fe substitution on the clinopyroxene crystal structure was studied in four clinopyroxenes with intermediate compositions between hedenbergite and ferrosilite. The major structural change is in the size and shape of the M2 polyhedron, while the M1 polyhedron remains unchanged. The decrease in the average size of the M2 polyhedron causes kinking of the tetrahedral chain and increases in the out-of-plane tilting of the basal face of the tetrahedron. The space group changes from C2/c to P2/c at about Fs80Wo20 composition. The anisotropic temperature factors may be explained by positional disorder.

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The effect of Ca-Fe substitution on the clinopyroxene crystal structure was studied in four clinopyroxenes with intermediate compositions between hedenbergite...

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  • File Format: PDF
  • File Size: 670 KB
  • Pages: 12
  • Language: EN
  • Total Downloads: 36
  • Last Updated: 3 weeks ago

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