Roper® DF Safety Data Sheet: Fungicide With Combustible Dust Hazards.pdf

Summary:

This SDS provides critical information on the safe use, handling, storage, and emergency response procedures for ROPER® DF, a Group M3 fungicide.

1. Identification:
- Product Identifier: EPA Registration No. 34704-1063, Trade Name: ROPER® DF
- Supplier: Loveland Products, Inc., P.O. Box 1286, Greeley, CO 80632-1286
- Emergency Contact:
- Chemical Emergency: 1-800-424-9300
- Medical Emergencies: 1-866-944-8565 (Product Information)
- Product Info/General Inquiries: 1-888-574-2878 (LPI-CUST)

2. Hazards Identification:
- Classification: Combustible Dust, Sensitization - Skin (Category 1 and 2)
- Hazard Statements:
- May form combustible dust concentrations in air.
- Suspected of damaging fertility of the unborn child.
- Precautionary Statements:
- Avoid breathing dust/fume/gas/mist/vapors/spray.
- Prevent contamination of work clothing.
- Wear protective gloves, clothing, eye, and face protection.
- Obtain special instructions before use.
- Store locked up and dispose of contents/container according to local regulations.

3. Composition and Ingredients:
- Substances: Mancozeb (8018-01-7), Hexamethylenetetramine (100-97-0)
- Concentrations: 75.00% Mancozeb, 2.70% Hexamethylenetetramine
- Other Ingredients: Proprietary or non-hazardous ingredients

4. First Aid Measures:
- General Advice: Seek medical attention if symptoms occur.
- Specific Symptoms and Treatment:
- Inhalation: Move to fresh air, give artificial respiration if necessary, call poison control center.
- Eye Contact: Rinse with water for 15-20 minutes, remove contact lenses (if possible), call poison control.
- Skin/Clothing Contact: Remove contaminated clothing, rinse skin with plenty of water for 15-20 minutes, seek medical advice.
- Emergency Contact: Call 1-866-844-8565 for medical emergencies involving this product.

5. Fire Fighting Measures:
- Extinguishing Media: Dry chemical, carbon dioxide (CO2), foam, water spray or fog.
- Special Hazards: Thermal decomposition may release hydrogen sulfide, oxides of carbon, sulfur, nitrogen, and other toxic gases.
- Firefighter Protection: Wear self-contained breathing apparatus, full protective gear, keep fire exposed containers cool, isolate fire area.

6. Accidental Release Measures:
- Personal Precautions: Avoid inhalation, skin/eye contact. Ensure adequate ventilation, wear suitable protective clothing.
- Environmental Precautions: Prevent water contamination from spills or disposal of equipment washwater. Do not apply directly to water or intertidal areas.
- Cleanup Methods:
- Large Spills: Sweep up and transfer to approved containers for disposal.
- Small Spills: Sweep up, transfer to approved containers, never return spills to original containers.

7. Handling and Storage:
- Precautions: Do not use near heat or open flame. Follow manufacturer’s instructions for cleaning PPE. Wash hands before eating/drinking after handling the product. Remove contaminated clothing immediately.