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cca_73_2000_575-584_Mlinaric.pdf

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Summary

11-Methylenepentacyclo[5.4.0.02,6.03,10.05,9]undecan-8-spiro-3'-diazirine (1) was synthesized and its photochemical decomposition in different media investigated. Irradiation of N2-purged benzene solution of diazirine 1 produced a mixture of four azine-isomers, while photolysis in pentane gave a mixture of hydrocarbons as the main insertion products and traces of 1,3-bishomopentaprismane. Photolysis in N2-matrix at –196 °C proved the formation of a diazo-compound, which upon warm-up gave traces of 1,3-bishomopentaprismane. The results suggest that the fate of the carbene depends on the reaction conditions.

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11-Methylenepentacyclo[5.4.0.02,6.03,10.05,9]undecan-8-spiro-3'-diazirine (1) was synthesized and its photochemical decomposition in different media...

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File Format: PDF
File Size: 199 KB
Pages: 10
Language: EN
Total Downloads: 48
Last Updated: 1 week ago

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