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Corrie15PhD.pdf
Preview of http://etheses.bh… 93/1/Corrie15PhD.pdf
🔗 Source: etheses.bham.ac.uk
📊 Size: 5.07 MB
👤 Author: Benjamin Corrie
⬇️ Downloads: 60

Summary

tetrahedrally coordinated A2MO4 oxides, apatite oxides, and brownmillerite type Ba2Sc2O5 systems. Powder X-ray diffraction showed successful incorporation of aluminium and gallium into Ba2GeO4 and Sr2GeO4, creating oxide ion vacancies and increasing ionic conductivity. Neutron diffraction and TGA studies indicated successful incorporation of water and fluorine into La8Sr2Ge6O26 and La8Sr2Si6O26 samples. Doping Ba2Sc2O5 with titanium stabilized an oxygen deficient perovskite structure, and doping with yttrium or ytterbium reduced the cost with negligible effect on ionic conductivity. Proton positions in hydrated BaSc0.25Y0.45Ti0.3O2.65 were located using neutron diffraction.

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tetrahedrally coordinated A2MO4 oxides, apatite oxides, and brownmillerite type Ba2Sc2O5 systems.

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  • File Format: PDF
  • File Size: 5.07 MB
  • Pages: 180
  • Language: EN
  • Author: Benjamin Corrie
  • Total Downloads: 60
  • Last Updated: 1 week ago

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