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Mayr’s Relativity Scales.pdf

2019_MayrPoster.pdf
Preview of Mayr’s relativity scales
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Summary

As escalas de reatividade mostram uma seleção de parâmetros de reatividade publicados E, N e sN, que permitem o cálculo das constantes de taxa para reações de combinação de eletrófilos com nucleófilos, com a equação: log k20°C = sN(N + E). As escalas podem ser lidas da seguinte forma: nucleófilos e eletrófilos localizados no mesmo nível (E + N = 0) combinam com constantes de taxa de k ≈ 1 M-1 s-1 a 20 °C, correspondendo a tempos de meia-reação de 10 segundos para soluções 0,1 M. Além disso, a 20 °C, eletrófilos geralmente não reagem com nucleófilos posicionados mais de 5 unidades acima, e eletrófilos geralmente sofrem reações controladas por difusão (freqüentemente inseletivas) com nucleófilos posicionados mais de 9 unidades abaixo.

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As escalas de reatividade mostram uma seleção de parâmetros de reatividade publicados E, N e sN, que permitem o cálculo das constantes de taxa para reações de...

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  • File Format: PDF
  • File Size: 364 KB
  • Pages: 1
  • Language: PT
  • Total Downloads: 150
  • Last Updated: 8 hours ago

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