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Noncentrosymmetric Mixed-cation Borate: Crystal Growth, Structure And Optical Properties Of Cs2Ca[B4O5(OH)4]2·8 H2O.pdf

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Preview of Noncentrosymmetric Mixed-cation Borate: Crystal growth, Structure and Optical Properties of Cs2Ca[B4O5(OH)4]2·8 H2O
🔗 Source: rsc.org
📊 Size: 768 KB
👤 Author: LXY
⬇️ Downloads: 27

Summary

The study presents a mediator-free, direct Z-scheme photocatalytic system utilizing an organic-inorganic hybrid photocatalyst composed of BiVO4 and g-C3N4. This binary mixture demonstrates highly efficient visible-light-induced photocatalytic activity for RhB degradation. The electronic properties of g-C3N4 and BiVO4 are analyzed, with band gap energies of 2.60 eV and 2.45 eV, respectively, indicating their potential for visible light absorption.

Scanning Electron Microscopy (SEM) images confirm the successful synthesis of the samples, showing distinct morphologies for g-C3N4 and BiVO4, and their composite mixture. The degradation curves of RhB over the photocatalysts reveal that the addition of chelating agents like TBA, EDTA, or BQ enhances the photocatalytic performance, suggesting the involvement of electron transfer processes in the Z-scheme mechanism.

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Description

A mediator-free, direct Z-scheme photocatalytic system utilizing an organic-inorganic hybrid photocatalyst, BiVO4/g-C3N4, demonstrates highly efficient visible-light-induced activity, as evidenced in the supplementary material.

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  • File Format: PDF
  • File Size: 768 KB
  • Pages: 4
  • Language: EN
  • Author: LXY
  • Total Downloads: 27
  • Last Updated: 6 days ago

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Noncentrosymmetric guideNoncentrosymmetric tutorialMixed-cation guideMixed-cation tutorialBorate: guideBorate: tutorialCrystal guideCrystal tutorialgrowth, guidegrowth, tutorialStructure guideStructure tutorialOptical guideOptical tutorialProperties guideProperties tutorialCs2Ca[B4O5(OH)4]2·8 guideCs2Ca[B4O5(OH)4]2·8 tutorial

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