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Pentamethylcyclopent Adienyl Antimony.pdf

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Summary

Pentamethylcyclopentadienyl antimony(III) cations [Cp2Sb][B(C6F5)4], [Cp2Sb][OTf], [CpSbCl][B(C6F5)4], and [CpSb][OTf]2 have been isolated and structurally characterized, with [CpSbCl]+ forming dimers in the solid state via an intermolecular Sb-Cl interaction. [CpSbCl][B(C6F5)4] is significantly Lewis acidic and can catalyze the dimerization of 1,1-diphenylethylene, while [Cp2*Sb][B(C6F5)4] exhibits negligible Lewis acidity.

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Description

Pentamethylcyclopentadienyl antimony(III) cations [Cp*2Sb][B(C6F5)4], [Cp2*Sb][OTf], [Cp*SbCl][B(C6F5)4], and [Cp*Sb][OTf]2 have been isolated and structurally...

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  • File Format: PDF
  • File Size: 760 KB
  • Pages: 5
  • Language: EN
  • Total Downloads: 35
  • Last Updated: 2 days ago

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