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Prvotnega Spletišča.pdf

JCAT-13-716_revised_06Dec2013.pdf
Preview of prvotnega spletišča
🔗 Source: pubman.mpdl.mpg.de
📊 Size: 5.68 MB
👤 Author: Evelyn Prohn
⬇️ Downloads: 169

Summary

MoVTeNb oxide catalysts, exclusively composed of the M1 phase, were studied in the direct oxidation of propane to acrylic acid under various reaction conditions. The catalyst showed high stability and selectivity due to its phase purity and homogeneity. The reaction network was found to be less complex compared to less-defined catalysts, with the main route to acrylic acid being the oxidative dehydrogenation of propane to propene followed by allylic oxidation of propene. Oxygen partial pressure and auxiliary steam were identified as important process parameters that control the activity and selectivity of the catalyst. The addition of steam caused enrichment of V and Te on the surface, and surface vanadium became more oxidized, correlating with the abundance of acrylic acid detected.

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MoVTeNb oxide catalysts, exclusively composed of the M1 phase, were studied in the direct oxidation of propane to acrylic acid under various reaction...

Technical Information

  • File Format: PDF
  • File Size: 5.68 MB
  • Pages: 51
  • Language: EN
  • Author: Evelyn Prohn
  • Total Downloads: 169
  • Last Updated: 3 weeks ago

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