Xenon NMR Studies.pdf

129xe_nmr_studies_of_hyper-cross-linked_polyarylcarbinols-_rigid_versus_flexible_structures.pdf
Preview of Xenon NMR Studies
🔗 Source: pines.berkeley.edu
📊 Size: 961 KB
📄 Pages: 8 pages
⬇️ Downloads: 50

Summary

Xenon NMR is used to study hyper-cross-linked polyarylcarbinols, showing that rigid-rod connecting units are necessary for microporosity, and flexible structures have conventional surface areas and xenon NMR spectra. A microporous polymer based on rigid triarylcarbinol monomers exhibits high xenon uptake and a linear chemical shift variation with pressure. The data are compared to two possible models of the polymer microstructure, one involving loosely cross-linked microporous particles and the other a homogeneous polymer with a uniform pore size distribution.

Description

Xenon NMR is used to study hyper-cross-linked polyarylcarbinols, showing that rigid-rod connecting units are necessary for microporosity, and flexible...

Technical Information

  • File Format: PDF
  • File Size: 961 KB
  • Pages: 8
  • Language: EN
  • Total Downloads: 50
  • Last Updated: 1 week ago

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