Section 1 – Chemical Product and Company Identification
Product Name: C.A.L.F.A®
Chemical Name: Mixture
Common Name, Synonym: Carboxylic Acids
Material Uses: Fertilizer Adjuvant
Manufacturer/Manufactured For: Miller Chemical and Fertilizer, LLC
Phone: (717) 632‐8921 FAX: (717) 646‐1104 CHEMTREC: (800) 424‐9300
Section 2 – Composition/Information on Ingredients
2.1 Classification of the substance or mixture
GHS Classification (29 CFR 1910.1200)
Skin Irritation (Category 2)
Eye Irritation (Category 2B)
2.2 Label elements
GHS Labeling Elements
Pictogram:
Signal Word: Warning
Hazard Statements: Causes skin irritation. Causes eye irritation.
Precautionary Statements: Wash skin thoroughly after handling. Wear protective gloves. If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs or eye irritation persists: Get medical attention. Wash contaminated clothing before reuse.
Section 3 – Hazards Identification
The above mixture has been determined to be hazardous according to GHS bridging principles.
PA Right to Know: This product contains proprietary ingredients.
This product contains the following chemicals subject to the reporting requirements of Section 13Title III of the Superfund Amendments and Reauthorization act of 1986 and 40 CFR part 372 ( the corresponding CAS numbers and typical percent by weight are also provided).
None Established
Ingredient Name
CAS Number
%
Mixture of Carboxylic Acids
None Established
>10%
Product Name: C.A.L.F.A®
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Section 4 – First Aid Measures
EYE CONTACT
Immediately flush eyes with plenty of water for at least 15 minutes, while holding eyelids apart to ensure flushing of entire surface. Call a physician.
SKIN CONTACT
Immediately flush skin with plenty of water for at least 15 minutes, while removing contaminated clothing and shoes. Thoroughly clean clothing and shoes before reuse. Call a physician.
INHALATION
Remove to fresh air. If not breathing give artificial respiration, preferably mouth to mouth. If breathing is difficult give oxygen. Call a physician.
INGESTION
If swallowed, DO NOT induce vomiting. Rinse mouth with water. Dilute stomach contents by drinking water. If vomiting occurs spontaneously, keep head bellow hips to prevent breathing vomit into lungs.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Call a physician immediately!
Section 5 – Fire‐Fighting Measures
Flash Point (METHOD):
Not Available
Auto‐Ignition:
Not Available
Flammable Limits:
Not Available
Extinguishing Media:
Use alcohol foam, carbon dioxide, water fog, dry chemical, or halon when fighting fires involving this material.
Special Fire Fighting Procedures:
None currently known.
Unusual Fire and Explosion Hazards:
Oxides of carbon may be generated.
Section 6 – Accidental Release Measures
Personal precautions
Evacuate non‐essential personnel, eliminate ignition sources, and wear protective equipment (See Section VIII). Shut off source of leak only if safe to do so. Wear respiratory equipment if exposure limits are exceeded.
Contain spill
Recover free product. To clean up residue, flush sparingly with water or use an absorbent. Avoid runoff to ground water, surface waters, and sewers. It may be necessary to remove contaminated soil. If product is flammable or combustible, use non‐sparking tools. If required, notify state and local authorities.
Section 6 – Accidental Release Measures continued
Disposal Method
Solids must be disposed of in a permitted waste management facility. Recovered liquids may be reprocessed or incinerated. Incineration must be handled in a permitted facility. Dispose of material in accordance with all Federal, State and Local regulations. Local regulations may be more stringent than Federal or State.
Section 7 – Handling and Storage
Handling
Wear protective equipment when handling. Wash thoroughly after handling. Do not get in eyes. Do not breathe vapor, mist, or dust. Avoid prolonged or repeated contact with skin. Do not swallow.
Storage
For industrial use only. Keep container closed when not in use. Store in a cool dry place. Keep out of reach of children.
Product Name: C.A.L.F.A®
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Section 8 – Exposure Controls/Personal Protection
Engineering Controls
Mechanical
Mechanical ventilation is preferred.
Respiratory Protection
If exposure limits are exceeded, or if exposure may occur, use a NIOSHA/MSHA respirator approved for your conditions of exposure.
Refer to the most recent NIOSHA publications concerning chemical hazards, or consult your safety equipment supplier. Respiratory protection programs must be in compliance with OSHA requirements in 29 CFR 1910.134. For emergencies, a NIOSHA/MSHA approved positive pressure‐breathing apparatus should be readily available.
Eye Protection
Chemical goggles or face shield. Always wear eye protection when working with chemicals. Never wear contact lenses when working with chemicals.
Skin Protection
Rubber gloves. Clean protective body covering, rubber apron, and rubber boots.
Work Hygienic Practices
Avoid contact with skin, eyes, and clothing. After handling this product, wash hands before eating, dr
