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Stereoselective Synthesis Of Tertiary Chlorides From Fluoroenes And Isoprene.pdf

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Preview of Stereoselective Synthesis of Tertiary Chlorides from Fluoroenes and Isoprene
🔗 Source: epub.ub.uni-muenchen.de
📊 Size: 345 KB
📄 Pages: 5 pages
⬇️ Downloads: 30

Summary

The article describes the synthesis of two new compounds, tertiary chlorides 8 and Y-2, from a reaction involving allylic chlorides 6a and 6b. The process involves several steps:

1. Synthesis of 6a and 6b: A 2:1 mixture of allylic chlorides 6a and 6b was obtained by reacting vanaspere with concentrated hydrobromic acid at a controlled temperature.

2. Stereoselective Cyclization: The reaction of 6a.b (obtained from the previous step) with isoprene in the presence of ZnCl/Et,O catalyst yielded an 85:15 mixture of tertiary chlorides 8 (mixture of 8-2 and Y-2).

3. Purification and Characterization: The mixture was analyzed using nuclear magnetic resonance (NMR) spectroscopy to assign configurations and confirm the structures of the compounds.

4. Conclusion: The authors conclude that the reaction proceeds with stereoselectivity, influenced by the isoprene's double bond configuration, leading to specific arrangements of substituents on the resulting chlorides.

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Description

The Institute for Chemical Derivatives at the University of Lübeck reports the synthesis of novel compounds, including B- and Y,-type mumlmes, through electrochemical methods and the use of specific chlorides.

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  • File Format: PDF
  • File Size: 345 KB
  • Pages: 5
  • Language: EN
  • Total Downloads: 30
  • Last Updated: 3 months ago

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