Magnetic Properties Of Transition Metal Centers: From Atoms To Complex Molecules.pdf

Phys.Kolloquium_Lau_Dittmaier_17-12-2018_Antrittsvorl.pdf
Preview of Magnetic Properties of Transition Metal Centers: From Atoms to Complex Molecules
🔗 Source: mathphys.uni-freiburg.de
📊 Size: 109 KB
👤 Author: Matthias Weidemüller
⬇️ Downloads: 31

Summary

Prof. Dr. Tobias Lau from the Physics Institute, University of Freiburg, discusses his research on transition metals, highlighting their diverse magnetic orders, multiple oxidation states, and significance as active centers in metalloenzymes. His team investigates the electronic and magnetic properties of these transition metal centers across various scales: single atoms, diatomic molecules, small clusters, chelates, and organometallic complexes.

The goal is to understand energy levels, spin states, oxidation states, and valence electron delocalization in 3d and 4f transition element coordination entities, enabling the manipulation of electronic and magnetic properties. They utilize core-level excitation techniques for local and element-specific analysis of electronic structures in ultra-dilute gaseous, solvated, and liquid samples.

Their methods include:
- Cryogenic ion trap setup for gas-phase soft X-ray absorption (XAS) and x-ray magnetic circular dichroism (XMCD) spectroscopy.
- Liquid-jet setup for resonant inelastic X-ray scattering (RIXS) at BESSY II.

These techniques allow them to track ligand-by-ligand coordination changes from unsaturated to saturated complexes, directly observing the impact of coordination and solvation on metal center properties, such as spin state and oxidation state shifts.

Description

Transition metals' magnetic behavior and electronic properties explored from single atoms to complex organometallic entities, aiming for fundamental insights into energy levels and spin states.

Technical Information

  • File Format: PDF
  • File Size: 109 KB
  • Pages: 1
  • Language: EN
  • Author: Matthias Weidemüller
  • Total Downloads: 31
  • Last Updated: 3 weeks ago

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